Electrostatic models in the theory of solutions Export

@article{citeulike:4863686, abstract = {A critical analysis of current methods for dealing with the problem of electrostatic field calculations for systems of charged particles in dielectric media is presented. The applicability of the approximation which assumes the identity of the field created by the charges in vacuum and the induction vector-broadly used in electrostatic calculations in solution theory-is analysed. There are then discussed three cavity models which describe the medium as: (i) local uniform dielectric (?= const), (ii) local nonuniform dielectric (?=?(r)), (iii) dielectric with spatial dispersion (?(r, r[prime or minute])).}, author = {Kharkats, Yu and Kornyshev, A. A. and Vorotyntsev, M. A.}, citeulike-article-id = {4863686}, citeulike-linkout-0 = {http://dx.doi.org/10.1039/F29767200361}, citeulike-linkout-1 = {http://www.rsc.org/Publishing/Journals/article.asp?doi=F29767200361}, doi = {10.1039/F29767200361}, journal = {J. Chem. Soc., Faraday Trans. 2}, keywords = {electrostatics, implicit\_solvation}, pages = {361--371}, posted-at = {2009-06-16 01:16:46}, priority = {2}, publisher = {The Royal Society of Chemistry}, title = {Electrostatic models in the theory of solutions}, url = {http://dx.doi.org/10.1039/F29767200361}, volume = {72}, year = {1976} }

TY - JOUR ID - citeulike:4863686 L3 - citeulike-article-id:4863686 N2 - A critical analysis of current methods for dealing with the problem of electrostatic field calculations for systems of charged particles in dielectric media is presented. The applicability of the approximation which assumes the identity of the field created by the charges in vacuum and the induction vector-broadly used in electrostatic calculations in solution theory-is analysed. There are then discussed three cavity models which describe the medium as: (i) local uniform dielectric (?= const), (ii) local nonuniform dielectric (?=?(r)), (iii) dielectric with spatial dispersion (?(r, r[prime or minute])). JF - J. Chem. Soc., Faraday Trans. 2 EP - 371 TI - Electrostatic models in the theory of solutions PB - The Royal Society of Chemistry VL - 72 SP - 361 KW - electrostatics KW - implicit_solvation AU - Kharkats, Yu AU - Kornyshev, AA AU - Vorotyntsev, MA PY - 1976/// UR - http://dx.doi.org/10.1039/F29767200361 ER -