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Theory of the rotational Brownian motion of a linear molecule in 3D. I. Relaxation and steady-state regimes

by: M. N. Hounkonnou, A. Ronveaux, P. Navez
Journal of Physics A: Mathematical and General, Vol. 27, No. 20. (01 January 1999), 6635, doi:10.1088/0305-4470/27/20/006  Key: citeulike:11565342

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Abstract

Exact analytical expressions for the dielectric and Kerr functions in both relaxation and steady-state regimes are explicitly calculated by solving the Fokker-Planck-Kramers (FPK) equation for the rotational Brownian motion of a linear rigid rotor in 3D. The response functions thus obtained generalize and extend all the results recently published on the topic. The particular cases of the Debye-Smoluchowski and Rocard diffusion models are straightforwardly recovered.


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