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Adv. Synth. Catal., Vol. 349, No. 14-15. (8 October 2007), pp. 2241-2246, doi:10.1002/adsc.200700223 Key: citeulike:11893272
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A catalyst generated from copper(I) oxide and 4,7-diphenyl-1,10-phenanthroline for the first time allows the catalytic protodecarboxylation even of deactivated aromatic carboxylic acids, giving rise to the corresponding arenes. Based on DFT calculations, a reaction pathway is proposed that accurately reflects the experimental results, such as the observed reactivity order of the substrates.
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