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π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet

by: Tetsuya Kambe, Ryota Sakamoto, Ken Hoshiko, Kenji Takada, Mariko Miyachi, Ji-Heun Ryu, Sono Sasaki, Jungeun Kim, Kazuo Nakazato, Masaki Takata, Hiroshi Nishihara
J. Am. Chem. Soc. In Journal of the American Chemical Society (29 January 2013), doi:10.1021/ja312380b  Key: citeulike:12005120

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Abstract

A π-conjugated nanosheet comprising planar nickel bis(dithiolene) complexes was synthesized by a bottom-up method. A liquid?liquid interfacial reaction using benzenehexathiol in the organic phase and nickel(II) acetate in the aqueous phase produced a semiconducting bulk material with a thickness of several micrometers. Powder X-ray diffraction analysis revealed that the crystalline portion of the bulk material comprised a staggered stack of nanosheets. A single-layer nanosheet was successfully realized using a gas?liquid interfacial reaction. Atomic force microscopy and scanning tunneling microscopy confirmed that the π-conjugated nanosheet was single-layered. Modulation of the oxidation state of the nanosheet was possible using chemical redox reactions.


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