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Creating precise 3D microstructures using laser direct-write bimetallic thermal resist grayscale photomasksedited by: Jim Fieret, Peter R. Herman, Tatsuo Okada, Craig B. Arnold, Friedrich G. Bachmann, Willem Hoving, Kunihiko Washio, Yongfeng Lu, David B. Geohegan, Frank Trager, Jan J. DubowskiPhoton Processing in Microelectronics and Photonics IV, Vol. 5713, No. 1. (2005), pp. 247-258.
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AbstractPrevious research demonstrated Sn/In and Bi/In bimetallic thermal resists are promising new materials for direct-write analogue grayscale photomask processes. These materials turn transparent with increased laser exposure power and their optical density changes smoothly from 3 OD when unexposed to less than 0.22 OD when fully exposed. The transparency is the result of an oxidation process that is controllable with exposure to generate the grayscale levels in the photomask. In order to produce precise 3D structures in regular photoresists, the steps involved in microlithography must be quantified and examined. The lithographic process includes drawing 8-bit grayscale bitmap patterns, computer-aided laser writing photomasks on bimetallic films, and regular photoresist exposure using a mask-aligner. Compensation during the mask-writing process was necessary since the relationship between the optical density of the exposed bimetallic films and the laser writing power was not completely linear. In addition, the response of the photoresists to the mask exposure time was also a non-linear relationship. To investigate the resolution limit for Bi/In and Sn/In bimetallic thermal resists as a masking material, we used a modified form of interference lithography to expose and develop structures in Bi/In resists with widths that are less than 200 nm. As a result of the lithography, we were able to create structures in the Bi/In films that are up to 20 times smaller than previously obtained using the direct-write method.
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