Nanomagnetic Control of Intersystem Crossing Export

@article{citeulike:5720519, abstract = {PMID: 19725575 A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing represents a form of heterogeneous catalysis that does not require molecular contact, but only short-range magnetic coupling.}, author = {Cohen, Adam E.}, citeulike-article-id = {5720519}, citeulike-linkout-0 = {http://dx.doi.org/10.1021/jp907113p}, citeulike-linkout-1 = {http://pubs.acs.org/doi/abs/10.1021/jp907113p}, doi = {10.1021/jp907113p}, journal = {The Journal of Physical Chemistry A}, keywords = {nanoparticles, photophysics, theory}, number = {0}, posted-at = {2009-09-04 02:52:11}, priority = {2}, title = {Nanomagnetic Control of Intersystem Crossing}, url = {http://dx.doi.org/10.1021/jp907113p}, volume = {0}, year = {0000} }

TY - JOUR ID - citeulike:5720519 L3 - citeulike-article-id:5720519 N2 - PMID: 19725575 A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing represents a form of heterogeneous catalysis that does not require molecular contact, but only short-range magnetic coupling. IS - 0 JF - The Journal of Physical Chemistry A TI - Nanomagnetic Control of Intersystem Crossing VL - 0 KW - nanoparticles KW - photophysics KW - theory AU - Cohen, Adam PY - 2000/// UR - http://dx.doi.org/10.1021/jp907113p ER -