Dynamic Monte Carlo Simulation on the Polymer Chain with One End Grafted on a Flat Surface Export

@article{citeulike:898884, abstract = {A linear polymer chain in good solvent condition with one end grafted on a infinitely large, impenetrable flat surface is investigated using dynamic Monte Carlo simulation on a simple cubic lattice. Chain shape and dimension, angular correlation between the direction of the end-to-end vector and that of the longest principal axis of inertia are studied and discussed. Results reveal that the asphericity of end-grafted polymer chains is greater than that of free ones, the limit ratio ?L12? : ?L22? : ?L32? is about 1 : 3.0 : 14.9. The limit of mean angle ?\&thetas;? of end-grafted chains is about 22°, smaller than that of free chains, indicating angular correlation between the direction of the end-to-end vector and that of the longest principal axis is reinforced.}, address = {Department of Chemistry, Zhejiang University, Hangzhou, 310027, China}, author = {Huang, Jianhua and Jiang, Wenhua and Han, Shijun}, citeulike-article-id = {898884}, citeulike-linkout-0 = {http://dx.doi.org/10.1002/1521-3919(20010401)10:4%3C339::AID-MATS339%3E3.0.CO;2-J}, citeulike-linkout-1 = {http://www3.interscience.wiley.com/cgi-bin/abstract/80002475/ABSTRACT}, doi = {10.1002/1521-3919(20010401)10:4%3C339::AID-MATS339%3E3.0.CO;2-J}, journal = {Macromolecular Theory and Simulations}, keywords = {grafted}, number = {4}, pages = {339--342}, posted-at = {2006-10-16 09:28:02}, priority = {2}, title = {Dynamic Monte Carlo Simulation on the Polymer Chain with One End Grafted on a Flat Surface}, url = {http://dx.doi.org/10.1002/1521-3919(20010401)10:4%3C339::AID-MATS339%3E3.0.CO;2-J}, volume = {10}, year = {2001} }

TY - JOUR ID - citeulike:898884 L3 - citeulike-article-id:898884 N2 - A linear polymer chain in good solvent condition with one end grafted on a infinitely large, impenetrable flat surface is investigated using dynamic Monte Carlo simulation on a simple cubic lattice. Chain shape and dimension, angular correlation between the direction of the end-to-end vector and that of the longest principal axis of inertia are studied and discussed. Results reveal that the asphericity of end-grafted polymer chains is greater than that of free ones, the limit ratio ?L12? : ?L22? : ?L32? is about 1 : 3.0 : 14.9. The limit of mean angle ?&thetas;? of end-grafted chains is about 22°, smaller than that of free chains, indicating angular correlation between the direction of the end-to-end vector and that of the longest principal axis is reinforced. IS - 4 JF - Macromolecular Theory and Simulations AD - Department of Chemistry, Zhejiang University, Hangzhou, 310027, China EP - 342 TI - Dynamic Monte Carlo Simulation on the Polymer Chain with One End Grafted on a Flat Surface VL - 10 SP - 339 KW - grafted AU - Huang, Jianhua AU - Jiang, Wenhua AU - Han, Shijun PY - 2001/// UR - http://dx.doi.org/10.1002/1521-3919(20010401)10:4%3C339::AID-MATS339%3E3.0.CO;2-J ER -