Enhanced surface hydrophobicity by coupling of surface polarity and topography Export

@article{citeulike:6045920, abstract = {10.1073/pnas.0905468106 We use atomistic computer simulation to explore the relationship between mesoscopic (liquid drop contact angle) and microscopic (surface atomic polarity) characteristics for water in contact with a model solid surface based on the structure of silica. We vary both the magnitude and direction of the solid surface polarity at the atomic scale and characterize the response of an aqueous interface in terms of the solvent molecular organization and contact angle. We show that when the topography and polarity of the surface act in concert with the asymmetric charge distribution of water, the hydrophobicity varies substantially and, further, can be maximal for a surface with significant polarity. The results suggest that patterning of a surface on several length scales, from atomic to \^{I}¼m lengths, can make important independent contributions to macroscopic hydrophobicity.}, author = {Giovambattista, Nicolas and Debenedetti, Pablo G. and Rossky, Peter J.}, citeulike-article-id = {6045920}, citeulike-linkout-0 = {http://dx.doi.org/10.1073/pnas.0905468106}, citeulike-linkout-1 = {http://www.pnas.org/content/106/36/15181.abstract}, citeulike-linkout-2 = {http://www.pnas.org/content/106/36/15181.full.pdf}, citeulike-linkout-3 = {http://view.ncbi.nlm.nih.gov/pubmed/19706474}, citeulike-linkout-4 = {http://www.hubmed.org/display.cgi?uids=19706474}, day = {8}, doi = {10.1073/pnas.0905468106}, journal = {Proceedings of the National Academy of Sciences}, keywords = {electrostatics, nonpolar, solvation}, month = {September}, number = {36}, pages = {15181--15185}, posted-at = {2009-10-31 00:58:41}, priority = {2}, title = {Enhanced surface hydrophobicity by coupling of surface polarity and topography}, url = {http://dx.doi.org/10.1073/pnas.0905468106}, volume = {106}, year = {2009} }

TY - JOUR ID - citeulike:6045920 L3 - citeulike-article-id:6045920 N2 - 10.1073/pnas.0905468106 We use atomistic computer simulation to explore the relationship between mesoscopic (liquid drop contact angle) and microscopic (surface atomic polarity) characteristics for water in contact with a model solid surface based on the structure of silica. We vary both the magnitude and direction of the solid surface polarity at the atomic scale and characterize the response of an aqueous interface in terms of the solvent molecular organization and contact angle. We show that when the topography and polarity of the surface act in concert with the asymmetric charge distribution of water, the hydrophobicity varies substantially and, further, can be maximal for a surface with significant polarity. The results suggest that patterning of a surface on several length scales, from atomic to μm lengths, can make important independent contributions to macroscopic hydrophobicity. IS - 36 JF - Proceedings of the National Academy of Sciences EP - 15185 TI - Enhanced surface hydrophobicity by coupling of surface polarity and topography VL - 106 SP - 15181 KW - electrostatics KW - nonpolar KW - solvation AU - Giovambattista, Nicolas AU - Debenedetti, Pablo AU - Rossky, Peter PY - 2009/09/08/ UR - http://dx.doi.org/10.1073/pnas.0905468106 ER -