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J. Polym. Sci. Polym. Phys. Ed., Vol. 15, No. 3. (1 March 1977), pp. 477-483, doi:10.1002/pol.1977.180150307 Key: citeulike:8028260
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The problem of a polyelectrolyte near the rod limit is formulated incorporating both the short-range stiffness of the backbone (the “wormlike chain”) and the electrostatic interaction between segments taken as a Debye–Húckel potential. By the use of a physically valid approximation an expression is derived for the mean-square extension length of a short polyelectrolyte chain. Some remarks are made on the relationship between the electrostatic interaction and the usual excluded-volume problem for polymer solutions.
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