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Ionization of Xenon Rydberg Atoms at a Metal Surface Export

Physical Review Letters, Vol. 85, No. 25. (18 December 2000), 5444.

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electric-fields ionization rydberg surface-effects

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Experiments in which a thermal-energy beam of xenon Rydberg atoms is directed at near grazing incidence onto a flat Au(111) surface are described that provide new insight into charge transfer and electron tunneling during atom/surface interactions. Analysis of the data shows that for the present range of principal quantum number n ; 13≤ n ≤20; ionization occurs at an atom/surface separation Z i  =  (4.5±0.9) n 2 a 0 ; where n 2 a 0 is the Bohr radius of the atom. This result is in good agreement with the value Z i ∼3.8 n 2 a 0 predicted by ab initio hydrogenic theory.


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