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Highly Diastereoselective anti-Aldol Reactions of Glycolate Titanium Enolates Export

by: Dnyaneshwar Gawas, Uli Kazmaier
The Journal of Organic Chemistry, Vol. 74, No. 4. (20 February 2009), pp. 1788-1790.

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PMID: 19125691 Diastereoselective aldol reactions of enolates of α-hydroxy ester with different aldehydes are metal tunable, providing either anti- or syn- products. The highest anti-selectivities were obtained with TiCl(OiPr)3, while Ti(OiPr)4 provides the opposite syn-products.


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