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A direct experimental method has been used to determine the magnitudes of the ice-water vapour, ice-water, and ice-ice (grain boundary) surface free energies. The magnitudes were found to be 109, <b>33</b> and 65 erg/cm<sup>2</sup>, respectively, at 0°C. The experimental results indicate that the grain boundary surface free energy varies slightly with the mismatch between the grains but that variations with crystal orientation of the ice-water vapour and the ice-water surface free energies are small.
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