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Synthesis of Gold Nanosheets at a Liquid/Liquid Interface Using an Amphiphilic Polyoxometallate/Surfactant Hybrid Photocatalystby: Tetsuya Kida
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AbstractAbstract: Control of the morphology of gold nanoparticles has received considerable attention because the physical and chemical properties of gold depend significantly on its size and shape. A novel route for obtaining 2-D gold nanostructures has been developed in which chloroaurate ions (AuCl4) are reduced at the 2-D interface between water and chloroform using an amphiphilic polyoxometallate (SiW12O404)/surfactant (dimethyldioctadecylammonium; DODA) hybrid photocatalyst under UV irradiation at room temperature in air. This simple method can readily produce large single-crystalline gold nanosheets (lateral size, ca. 20 ¼m; thickness, ca. 150 nm).
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