Glass transition and chain mobility in thin polymer films Export

@article{roth05, abstract = {We review recent work on the motion of polymer molecules confined to thin films. There has been considerable experimental evidence for large reductions in the glass transition temperature Tg with decreasing film thickness, indicative of enhanced segmental motion, while the motion of entire molecules is essentially unchanged from that in bulk samples. General trends in the data are highlighted and outstanding issues are discussed.}, author = {Roth, Connie B. and Dutcher, John R.}, booktitle = {International Symposium on Material Processing for Nanostructured Devices 2003}, citeulike-article-id = {2301586}, citeulike-linkout-0 = {http://dx.doi.org/10.1016/j.jelechem.2004.03.003}, citeulike-linkout-1 = {http://linkinghub.elsevier.com/retrieve/pii/S0022072804001457}, citeulike-linkout-2 = {http://www.sciencedirect.com/science/article/B6TGB-4CCNWGS-1/2/6823dfed198786df95bddc076dfac8d8}, day = {1}, doi = {10.1016/j.jelechem.2004.03.003}, journal = {Journal of Electroanalytical Chemistry}, keywords = {confinement, polymer, review}, month = {October}, number = {1}, pages = {13--22}, posted-at = {2008-11-20 20:38:30}, priority = {2}, title = {Glass transition and chain mobility in thin polymer films}, url = {http://dx.doi.org/10.1016/j.jelechem.2004.03.003}, volume = {584}, year = {2005} }

TY - JOUR ID - roth05 L3 - citeulike-article-id:2301586 N2 - We review recent work on the motion of polymer molecules confined to thin films. There has been considerable experimental evidence for large reductions in the glass transition temperature Tg with decreasing film thickness, indicative of enhanced segmental motion, while the motion of entire molecules is essentially unchanged from that in bulk samples. General trends in the data are highlighted and outstanding issues are discussed. IS - 1 JF - Journal of Electroanalytical Chemistry EP - 22 TI - Glass transition and chain mobility in thin polymer films VL - 584 T2 - International Symposium on Material Processing for Nanostructured Devices 2003 SP - 13 KW - confinement KW - polymer KW - review AU - Roth, Connie AU - Dutcher, John PY - 2005/10/01/ UR - http://dx.doi.org/10.1016/j.jelechem.2004.03.003 ER -