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Shear melting of a colloidal glass Export

unpublished (2009)

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colloids glass shear

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We explore the microscopic nature of shear melting of colloidal glasses using confocal microscopy.We find that shear melting, which occurs at strains of ∼ 8%, coincides with a strongly non-Gaussian step size distribution, reflecting cooperative motions of ∼ 3 particles. For large strainsthe particle mean square displacement increases linearly with strain and the step size distribution isGaussian; the applied shear thus drives diffusive behavior. The effective diffusion coefficient variesapproximately linearly with shear rate, consistent with a modified Stokes-Einstein relationship inwhich thermal energy is replaced by shear energy and the length-scale is set by the size of thecooperative regions.


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