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J. Am. Chem. Soc. In Journal of the American Chemical Society, Vol. 135, No. 5. (15 January 2013), pp. 1891-1894, doi:10.1021/ja310718f Key: citeulike:12193112
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A highly enantio- and diastereoselective synthesis of indolo- and benzoquinolizidine compounds has been developed through the formal aza-Diels?Alder reaction of enones with cyclic imines. This transformation is catalyzed by a new bifunctional primary aminothiourea that achieves simultaneous activation of both the enone and imine reaction components.
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