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Diels-Alder Reactions of Quinol Lactones: A Change of Regioselectivity with Stannic Chloride Catalysis Export

edited by: Org, Web

Journal of Organic Chemistry, Vol. 67, No. 26. (5 December 2002), pp. 9475-9476.

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Lewis acid-mediated Diels-Alder reactions of quinol lactone 2 gave regioselectivity opposite to that of the uncatalyzed reaction. Compound 12 is proposed as the reactive intermediate generated by the reaction of 2 with stannic chloride.


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